Confinement of particles to small regions of space for long
periods of time makes possible many high-accuracy experiments
whose results are on the cutting edge of research in physics.
The pertinent fields of research include molecular spectroscopy,
quantum electrodynamics, plasma behavior, the size of elementary
particles, and heavy ion storage [13][14][4][12].
Ions, or electrically charged particles, can be confined for these
types of experiments by electric and/or magnetic
fields without the difficulties introduced
by collisions with physical walls.
Both the Paul trap and
the Penning trap have been used successfully as ion traps. The geometry
of the traps is shown in Fig. 1: an electric potential
difference
is applied across
electrodes whose surfaces are defined by
hyperboloids of revolution about the -axis, typically
with
[13].
The Paul trap has an oscillating electric potential of:
where ,
, and
are spatial coordinates;
represents time;
is in the radio frequency range;
is a constant (DC)
electric potential; and
is the amplitude of an oscillating (AC)
electric potential.
The electric potential of the Penning trap is constant with respect to time and depends only on position:
In addition to an electric field, the Penning trap contains a constant
magnetic field directed along the
-axis.
The force acting on a single ion in a Paul trap is given by the
scalar product of the ion's charge and the electric field;
the electric field equals the
negative gradient
of the potential:
where î, j, and k are the unit vectors along the -,
-, and
-axes,
respectively, and
is the charge of the ion. The oscillating polarity of
the Paul trap's electric potential results in a force
which alternately focuses the radial
and axial (-axis) displacement of the ion.
A single ion in a Penning trap is influenced both by its constant electric field, which restricts the ion's axial position, and by a magnetic force whose magnitude and direction are given by:
where v is the vector representing the ion's velocity
and B is the magnetic field, which is a vector directed parallel
to the -axis.
When a collection of ions is trapped, one must also consider the
forces of interaction between ions. The Coulomb force describes the
interactive force on a charge in a collection of
point charges:
where is a constant,
and
are the position vectors of particles
and
,
and
are the particles' charges, and
is the unit direction vector from particle
to
.
Trapped ions display a variety of interesting behaviors,
depending on parameters including: the charge of the ions, the mass of the
ions, the temperature at which the experiment is conducted, the size of
the trap, the amplitude of electric and/or magnetic fields, and the
frequency of field oscillation (in the case of the Paul trap).
For example, an ion may oscillate periodically or
chaotically
with respect to the
-axis. Similarly, the radial position of an
ion may vary periodically or chaotically. When atoms are closely
coupled - that is, when the energy associated with ion interactions
is large compared to thermal energy - crystals may form. In other cases, the ions may escape the trap.